| Titre : |
Synthèse et propriétés d’organo-chélates tinctoriaux |
| Type de document : |
texte imprimé |
| Auteurs : |
Souheyla Chetioui, Auteur ; Djamil Azzeddine Rouag, Directeur de thèse |
| Editeur : |
جامعة الإخوة منتوري قسنطينة |
| Année de publication : |
2016 |
| Importance : |
338 f. |
| Format : |
30 cm. |
| Note générale : |
2 copies imprimées disponibles
|
| Langues : |
Français (fre) |
| Catégories : |
Français - Anglais
Chimie
|
| Tags : |
complexes organométalliques, ligands azoïques DRX RMN IR organometallic complexes azoic ligands chromophores XRD NMR المركبات الازوتية معقدات الأصباغ الاشعة السينية الاشعة تحت الحمراء الرنين المغناطيسي النووي |
| Index. décimale : |
540 Chimie et sciences connexes |
| Résumé : |
This doctoral thesis is devoted to the study of azo dyes and their organometallic complexes, which are a particular class of chemistry whose importance and interest to remain our considerable days. The dye industry is nowadays a permanent investigative sector that continues to grow.
The content of this thesis presents a contribution to the study of some coloring substances containing the chromophore azo -N = N- and their organometallic complexes subdivided as follows:
A general introduction, to position the interest of the subject, followed by a first chapter a bibliographic overview of dyes, azo dye compounds and their metal complexes history, generalities, application then we presented the various techniques experimental used.
The second chapter deals with the synthesis of a series of azo dyes followed by an analytical study of characteristic structures obtained by conventional spectroscopic methods: IR, 13C NMR, 1H NMR, UV-Visible, elemental microanalysis and a structural resolution and crystal X-ray diffraction study of new synthesized compounds.
The third chapter is devoted to the synthesis of a series of new organometallic complexes using the new chromogenic azo compounds synthesized as ligands with different metals as: Cu(II), Pd(II), Ni(II), followed by an analytical study of characteristic structures obtained by conventional spectroscopic methods: IR, 13C NMR, 1H NMR, UV-Visible, elemental microanalysis and a structural resolution and crystal X-ray diffraction study of new synthesized complexes.
The synthesized ligands are usually based on the skeleton of the azobenzene, they are aromatic or pseudo-aromatic systems linked by an azoic group (-N = N-). They are obtained by treating primary aromatic amines with nitrous acid, in a reaction known diazotization followed by diazo-coupling, these azo compounds obtained underwent complexation reaction with different metals: Cu(II), Pd(II), Ni(II) to yield organometallic complexes or metal-dyeing dyes.
|
| Diplôme : |
Doctorat en sciences |
| En ligne : |
../theses/chimie/CHE6977.pdf |
| Format de la ressource électronique : |
pdf |
| Permalink : |
https://bu.umc.edu.dz/md/index.php?lvl=notice_display&id=10375 |
Synthèse et propriétés d’organo-chélates tinctoriaux [texte imprimé] / Souheyla Chetioui, Auteur ; Djamil Azzeddine Rouag, Directeur de thèse . - جامعة الإخوة منتوري قسنطينة, 2016 . - 338 f. ; 30 cm. 2 copies imprimées disponibles
Langues : Français ( fre)
| Catégories : |
Français - Anglais
Chimie
|
| Tags : |
complexes organométalliques, ligands azoïques DRX RMN IR organometallic complexes azoic ligands chromophores XRD NMR المركبات الازوتية معقدات الأصباغ الاشعة السينية الاشعة تحت الحمراء الرنين المغناطيسي النووي |
| Index. décimale : |
540 Chimie et sciences connexes |
| Résumé : |
This doctoral thesis is devoted to the study of azo dyes and their organometallic complexes, which are a particular class of chemistry whose importance and interest to remain our considerable days. The dye industry is nowadays a permanent investigative sector that continues to grow.
The content of this thesis presents a contribution to the study of some coloring substances containing the chromophore azo -N = N- and their organometallic complexes subdivided as follows:
A general introduction, to position the interest of the subject, followed by a first chapter a bibliographic overview of dyes, azo dye compounds and their metal complexes history, generalities, application then we presented the various techniques experimental used.
The second chapter deals with the synthesis of a series of azo dyes followed by an analytical study of characteristic structures obtained by conventional spectroscopic methods: IR, 13C NMR, 1H NMR, UV-Visible, elemental microanalysis and a structural resolution and crystal X-ray diffraction study of new synthesized compounds.
The third chapter is devoted to the synthesis of a series of new organometallic complexes using the new chromogenic azo compounds synthesized as ligands with different metals as: Cu(II), Pd(II), Ni(II), followed by an analytical study of characteristic structures obtained by conventional spectroscopic methods: IR, 13C NMR, 1H NMR, UV-Visible, elemental microanalysis and a structural resolution and crystal X-ray diffraction study of new synthesized complexes.
The synthesized ligands are usually based on the skeleton of the azobenzene, they are aromatic or pseudo-aromatic systems linked by an azoic group (-N = N-). They are obtained by treating primary aromatic amines with nitrous acid, in a reaction known diazotization followed by diazo-coupling, these azo compounds obtained underwent complexation reaction with different metals: Cu(II), Pd(II), Ni(II) to yield organometallic complexes or metal-dyeing dyes.
|
| Diplôme : |
Doctorat en sciences |
| En ligne : |
../theses/chimie/CHE6977.pdf |
| Format de la ressource électronique : |
pdf |
| Permalink : |
https://bu.umc.edu.dz/md/index.php?lvl=notice_display&id=10375 |
|
Synthèse et propriétés d’organo-chélates tinctoriaux
