| Titre : |
Composes a transfert de protons : Synthese, structure et etude des differentes interactions interatomiques |
| Type de document : |
texte imprimé |
| Auteurs : |
Amani Direm, Auteur ; Nourredine Benali-cherif, Directeur de thèse |
| Editeur : |
جامعة الإخوة منتوري قسنطينة |
| Année de publication : |
2016 |
| Importance : |
330 f. |
| Format : |
30 cm. |
| Note générale : |
2 copies imprimées disponibles
|
| Langues : |
Français (fre) |
| Catégories : |
Français - Anglais
Chimie
|
| Tags : |
Composés à transfert de protons acides aminés aromatiques complexes de cuivre spectroscopie
FTIR diffraction des rayons X surface Hirshfeld calculs DFT Proton transfer compounds aromatic amino acids copper complexes FTIR spectroscopy X-rayon
diffraction Hirshfeld surface DFT calculations ?????? ??? ?????? ??????? ????? ?????? ?????? ????? ??? ???? ?????? ????????? ??? ??????? ?????? ??????
??????? ??????? ??????????? ?????? Hirshfeld????? ????? .DFT |
| Index. décimale : |
540 Chimie et sciences connexes |
| Résumé : |
This PhD thesis was dedicated to the synthesis and structural characterization using FTIR spectroscopy and single-crystals X-ray diffraction of new proton transfer compounds and copper coordination complexes. The first part of this manuscript concerns the synthesis and the characterization of three new proton transfer compounds, namely (P1, P2 and P3), by X-rays diffraction and FTIR spectroscopy. The intermolecular interactions within those compounds have been studied using the Hirshfeld surface. Concerning the second part, it is divided into two chapters, mainly reporting the crystal structures of two new coordination complexes (C1 and C2) based on copper and their FTIR spectra interpretations. The Hirshfeld surface analysis of both complexes has been investigated. Furthermore, the magnetic behavior of the two newly obtained complexes have been discussed.
Moreover, theoretical calculations by means of DFT methods of complex (C2) have been undertaken in order to optimize the geometrical parameters of the compound together with its IR and Raman vibration modes and a detailed comparative discussion has been given. |
| Diplôme : |
Doctorat en sciences |
| En ligne : |
../theses/chimie/DIR6893.pdf |
| Format de la ressource électronique : |
pdf |
| Permalink : |
https://bu.umc.edu.dz/md/index.php?lvl=notice_display&id=10222 |
|
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