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Partager le résultat de cette recherche Interroger des sources externesCaractérisations physico-chimiques et cinétique de bioactivité des biomateriaux / Fatima-Zohra Mezahi
Titre : Caractérisations physico-chimiques et cinétique de bioactivité des biomateriaux : hydroxyapatite & verre bioactif 54S4 élaboré par fusion et par voie sol-gel Type de document : texte imprimé Auteurs : Fatima-Zohra Mezahi ; Univ. de Constantine, Éditeur scientifique ; A. Harabi, Directeur de thèse Année de publication : 2009 Importance : 177 f. Note générale : 01 Disponible à la salle de recherche 02 Disponibles au magazin de la B.U.C. 01 CD Langues : Français (fre) Catégories : Français - Anglais
PhysiqueTags : Verre Hydroxyapatite Voie fusion Procédé sol-gel Bioactivité Solution physiologique Glass Melting process Sol gel process Bioactivity الهيدروكسيدأباتيت والزجاج طريقة الإنصهار سائل-هلام النشاط الحيوي السائل فيزيولوجي Index. décimale : 530 Physique Résumé : This work has been devoted to study the bioactive materials:
- The natural and synthetic hydroxyapatite.
- Quaternary glass 52S4: 52% SiO2- 30% CaO -14% Na2O- 4% P2O5 (wt%).
Among the main techniques used for both physical and chemical characterizations of these biomaterials are: the Induced Coupled Plasma (ICP-OES), X- Ray Diffraction (XRD), Scanning Electron Microscopy (SEM-EDS), Infra-Red spectroscopy (IR) and Nuclear Magnetic
Resonance (NMR).
The obtained results show that the hydroxyapatite bioactivity is controlled by several factors such as the density, trace elements and the second phase formation. In addition, mechanical properties optimization by adding inert oxides (ZrO2, TiO2 and Al2O3) is not always
accompanied by HA bioactivity improvement. It has been found that the presence of certain foreign oxides in the HA matrix inhibits “bone-like apatite” formation at the immerged HA surface in a Simulated Body Fluid (SBF).
As far as glasses are concerned, two synthesis routes have been used: the melting and sol-gel processes, which allow to obtain a porous glass with a large specific area. The immersion of these glasses in SBF and Phosphor Buffered Solution (PBS) has allowed to conclude that:
- the glasses synthesised by melting and sol-gel processes are bioactive, - the bioactivity kinetic is very sensitive to several factors, such as porosity, the dissolution kinetics of glasses and the ion concentrations of the immersion solution.
These work results confirm that glasses are more reactive than hydroxyapatite by carbonated apatite formation on its surface, in a very short time.Diplôme : Doctorat en sciences En ligne : ../theses/physique/MEZ5504.pdf Permalink : index.php?lvl=notice_display&id=3430 Caractérisations physico-chimiques et cinétique de bioactivité des biomateriaux : hydroxyapatite & verre bioactif 54S4 élaboré par fusion et par voie sol-gel [texte imprimé] / Fatima-Zohra Mezahi ; Univ. de Constantine, Éditeur scientifique ; A. Harabi, Directeur de thèse . - 2009 . - 177 f.
01 Disponible à la salle de recherche 02 Disponibles au magazin de la B.U.C. 01 CD
Langues : Français (fre)
Catégories : Français - Anglais
PhysiqueTags : Verre Hydroxyapatite Voie fusion Procédé sol-gel Bioactivité Solution physiologique Glass Melting process Sol gel process Bioactivity الهيدروكسيدأباتيت والزجاج طريقة الإنصهار سائل-هلام النشاط الحيوي السائل فيزيولوجي Index. décimale : 530 Physique Résumé : This work has been devoted to study the bioactive materials:
- The natural and synthetic hydroxyapatite.
- Quaternary glass 52S4: 52% SiO2- 30% CaO -14% Na2O- 4% P2O5 (wt%).
Among the main techniques used for both physical and chemical characterizations of these biomaterials are: the Induced Coupled Plasma (ICP-OES), X- Ray Diffraction (XRD), Scanning Electron Microscopy (SEM-EDS), Infra-Red spectroscopy (IR) and Nuclear Magnetic
Resonance (NMR).
The obtained results show that the hydroxyapatite bioactivity is controlled by several factors such as the density, trace elements and the second phase formation. In addition, mechanical properties optimization by adding inert oxides (ZrO2, TiO2 and Al2O3) is not always
accompanied by HA bioactivity improvement. It has been found that the presence of certain foreign oxides in the HA matrix inhibits “bone-like apatite” formation at the immerged HA surface in a Simulated Body Fluid (SBF).
As far as glasses are concerned, two synthesis routes have been used: the melting and sol-gel processes, which allow to obtain a porous glass with a large specific area. The immersion of these glasses in SBF and Phosphor Buffered Solution (PBS) has allowed to conclude that:
- the glasses synthesised by melting and sol-gel processes are bioactive, - the bioactivity kinetic is very sensitive to several factors, such as porosity, the dissolution kinetics of glasses and the ion concentrations of the immersion solution.
These work results confirm that glasses are more reactive than hydroxyapatite by carbonated apatite formation on its surface, in a very short time.Diplôme : Doctorat en sciences En ligne : ../theses/physique/MEZ5504.pdf Permalink : index.php?lvl=notice_display&id=3430 Exemplaires (1)
Code-barres Cote Support Localisation Section Disponibilité MEZ/5504 MEZ/5504 Thèse Bibliothèque principale Thèses Disponible
Titre : Modelisation et optimisation des capteurs solaires hybrides. Type de document : texte imprimé Auteurs : Amel Ghellab, Auteur ; Abdennacer Kabi, Directeur de thèse Editeur : جامعة الإخوة منتوري قسنطينة Année de publication : 2018 Importance : 120 f. Format : 30 cm. Note générale : 2 copies imprimées disponibles. Langues : Français (fre) Catégories : Français - Anglais
Génie ClimatiqueTags : Cellule PV capteur solaire verre PMMA air eau nanofluides modélisation simulation performances PV cell solar collector glass water nanofluids modeling الخلايا الكهروضوئية تجميع الطاقة الشمسية الزجاج الهواء الماء الناتو المانع النمذجة المحاكاة الأداء Index. décimale : 626 Génie Climatique Résumé : The growing in demand of energy risks exhausting totally different conventional fields, so in order to mitigate many states turn to deal with it and in the same time they wanted to maximize performance with less costs.
Thus we have developed a study highlighting the use of solar by introducing the hybrid photovoltaic / thermal collector consisting of a PV module under which a heat exchanger is provided to ensure the cooling of the cells.
The energy produced will be used to generate electricity and heat. At this stage we have studied the feasibility by taking two elements that are plastics as cover and nanofluids as cooling fluid.
Regarding plastics, these have proved to be the most widely used materials for the manufacture of various components, in particular those of solar heating ... etc.
As for nanofluids, it is a new technology that has revolutionized all those that have preceded it because they have high thermo physical properties.
At this stage, the study proposes the simulation of two different systems in forced convection inside the fluid channel, both for plastics and for nanofluids, the two systems proposed were based on the development of an energy balance between the different nodes of the system.
Hence the equations will be discretized and then introduced into a program written in Matlab for the purpose of calculating the unknowns and also being able to validate our results.
The results show that the use of PMMA is beneficial for transmitting more radiation compared to the glass and as for the nanofluids, the extraction of the heat under the panel proved to be better compared to the conventional fluids.
Diplôme : Doctorat en sciences En ligne : ../theses/gclim/GHE7207.pdf Format de la ressource électronique : Permalink : index.php?lvl=notice_display&id=10756 Modelisation et optimisation des capteurs solaires hybrides. [texte imprimé] / Amel Ghellab, Auteur ; Abdennacer Kabi, Directeur de thèse . - جامعة الإخوة منتوري قسنطينة, 2018 . - 120 f. ; 30 cm.
2 copies imprimées disponibles.
Langues : Français (fre)
Catégories : Français - Anglais
Génie ClimatiqueTags : Cellule PV capteur solaire verre PMMA air eau nanofluides modélisation simulation performances PV cell solar collector glass water nanofluids modeling الخلايا الكهروضوئية تجميع الطاقة الشمسية الزجاج الهواء الماء الناتو المانع النمذجة المحاكاة الأداء Index. décimale : 626 Génie Climatique Résumé : The growing in demand of energy risks exhausting totally different conventional fields, so in order to mitigate many states turn to deal with it and in the same time they wanted to maximize performance with less costs.
Thus we have developed a study highlighting the use of solar by introducing the hybrid photovoltaic / thermal collector consisting of a PV module under which a heat exchanger is provided to ensure the cooling of the cells.
The energy produced will be used to generate electricity and heat. At this stage we have studied the feasibility by taking two elements that are plastics as cover and nanofluids as cooling fluid.
Regarding plastics, these have proved to be the most widely used materials for the manufacture of various components, in particular those of solar heating ... etc.
As for nanofluids, it is a new technology that has revolutionized all those that have preceded it because they have high thermo physical properties.
At this stage, the study proposes the simulation of two different systems in forced convection inside the fluid channel, both for plastics and for nanofluids, the two systems proposed were based on the development of an energy balance between the different nodes of the system.
Hence the equations will be discretized and then introduced into a program written in Matlab for the purpose of calculating the unknowns and also being able to validate our results.
The results show that the use of PMMA is beneficial for transmitting more radiation compared to the glass and as for the nanofluids, the extraction of the heat under the panel proved to be better compared to the conventional fluids.
Diplôme : Doctorat en sciences En ligne : ../theses/gclim/GHE7207.pdf Format de la ressource électronique : Permalink : index.php?lvl=notice_display&id=10756 Exemplaires (1)
Code-barres Cote Support Localisation Section Disponibilité GHE/7207 GHE/7207 Thèse Bibliothèque principale Thèses Disponible
