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Titre : Adsorption du Bore en solution aqueuse par le charbon actif et l'alumine Type de document : texte imprimé Auteurs : Zelikha Bououden ; Université Mentouri, Editeur scientifique ; A. Mennour, Directeur de thèse Année de publication : 2007 Importance : 77 f. Note générale : 01 Disponible à la salle de recherche 02 Disponibles au magazin de la B.U.C. 01 CD Langues : Français (fre) Tags : Bore FTIR Adsorption Charbon actif Y-Alumine Index. décimale : 540 Chimie et sciences connexes Diplôme : Magistère En ligne : ../theses/chimie/BOU4885.pdf Permalink : https://bu.umc.edu.dz/md/index.php?lvl=notice_display&id=3726 Adsorption du Bore en solution aqueuse par le charbon actif et l'alumine [texte imprimé] / Zelikha Bououden ; Université Mentouri, Editeur scientifique ; A. Mennour, Directeur de thèse . - 2007 . - 77 f.
01 Disponible à la salle de recherche 02 Disponibles au magazin de la B.U.C. 01 CD
Langues : Français (fre)
Tags : Bore FTIR Adsorption Charbon actif Y-Alumine Index. décimale : 540 Chimie et sciences connexes Diplôme : Magistère En ligne : ../theses/chimie/BOU4885.pdf Permalink : https://bu.umc.edu.dz/md/index.php?lvl=notice_display&id=3726 Exemplaires
Code-barres Cote Support Localisation Section Disponibilité aucun exemplaire Etude de l'élimination de l'éthyle violet par adsorption sur la Kaolinite et le charbon actif et par des méthodes photochimiques en milieu aqueux / Abdessemed Ala
Titre : Etude de l'élimination de l'éthyle violet par adsorption sur la Kaolinite et le charbon actif et par des méthodes photochimiques en milieu aqueux Type de document : texte imprimé Auteurs : Abdessemed Ala ; Université Mentouri, Editeur scientifique ; Kamel Djebbar, Directeur de thèse Année de publication : 2009 Importance : 119 f. Note générale : 01 Disponible à la salle de recherche 02 Disponibles au magazin de la B.U.C. 01 CD Langues : Français (fre) Tags : Adsorption Kaolinite Photolyse Rayonnement UV Ethylle violet Charbon actif Sels H2O2 Index. décimale : 540 Chimie et sciences connexes En ligne : ../theses/chimie/ALa5423.pdf Permalink : https://bu.umc.edu.dz/md/index.php?lvl=notice_display&id=3777 Etude de l'élimination de l'éthyle violet par adsorption sur la Kaolinite et le charbon actif et par des méthodes photochimiques en milieu aqueux [texte imprimé] / Abdessemed Ala ; Université Mentouri, Editeur scientifique ; Kamel Djebbar, Directeur de thèse . - 2009 . - 119 f.
01 Disponible à la salle de recherche 02 Disponibles au magazin de la B.U.C. 01 CD
Langues : Français (fre)
Tags : Adsorption Kaolinite Photolyse Rayonnement UV Ethylle violet Charbon actif Sels H2O2 Index. décimale : 540 Chimie et sciences connexes En ligne : ../theses/chimie/ALa5423.pdf Permalink : https://bu.umc.edu.dz/md/index.php?lvl=notice_display&id=3777 Exemplaires
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Titre : Contribution de methodes destructives (Photolyse et P.O.A's) et non destructives à l'élimination de deux colorants (Bleu de methylène et rouge Congo) en solution aqueuse Type de document : texte imprimé Auteurs : Oualid Baghriche ; Université Mentouri, Editeur scientifique ; K.E. Djebbar, Directeur de thèse Année de publication : 2005 Importance : 133 f. Note générale : 01 Disponible à la salle de recherche 02 Disponibles au magazin de la bibliothèque centrale 01 CD Langues : Français (fre) Tags : Adsorption Photolyse Rayonnement UV Charbon actif Sels H2O2 BM+ S2O8 deus moins et alcools Index. décimale : 540 Chimie et sciences connexes En ligne : ../theses/chimie/BAG4234.pdf Permalink : https://bu.umc.edu.dz/md/index.php?lvl=notice_display&id=3728 Contribution de methodes destructives (Photolyse et P.O.A's) et non destructives à l'élimination de deux colorants (Bleu de methylène et rouge Congo) en solution aqueuse [texte imprimé] / Oualid Baghriche ; Université Mentouri, Editeur scientifique ; K.E. Djebbar, Directeur de thèse . - 2005 . - 133 f.
01 Disponible à la salle de recherche 02 Disponibles au magazin de la bibliothèque centrale 01 CD
Langues : Français (fre)
Tags : Adsorption Photolyse Rayonnement UV Charbon actif Sels H2O2 BM+ S2O8 deus moins et alcools Index. décimale : 540 Chimie et sciences connexes En ligne : ../theses/chimie/BAG4234.pdf Permalink : https://bu.umc.edu.dz/md/index.php?lvl=notice_display&id=3728 Exemplaires
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Titre : Elimination des polluants organiques par méthodes physicochimiques et photochimiques en milieux aqueux. : Cas de l’éthyle violet et du rouge congo (séparés et mélangés) et de la monochloramine Type de document : texte imprimé Auteurs : Abdessemed Ala, Auteur ; Kamel Djebbar, Auteur Editeur : جامعة الإخوة منتوري قسنطينة Année de publication : 2016 Importance : 224 f. Format : 30 cm. Note générale : 2 copies imprimées disponibles
Langues : Français (fre) Tags : Éthyle Violet Rouge Congo Mochloramine TiO2 Charbon actif ZnO Adsorption Rayonnement UV Photolyse H2O2 NaOCl •OH Ethyl violet Congo red Monochloramine Activated carbon UV radiation Photolysis Violet Ethyle) (Congo Rouge) ???????????? (NH2Cl) (PC500 TiO2) ????? ???? (ZnO) ?????? ???? ??? ??????? (H2O2) (NaOCl) (•OH ) (•Cl) Index. décimale : 540 Chimie et sciences connexes Résumé : The aim of this research is to study the decolorization of two dyes separated and in a mixture by physico-chemical processes (adsorption, TiO2 and CA-ZnO) and photocatalytic processes like: TiO2/UV and CA-ZnO/UV. Another study has been led on the degradation of Monocloramine in homogeneous phase via direct UV photolysis, H2O2/UV and
NaOCl/UV. Treated separately, both dyes have shown an appreciable adsorption on the two supports and that this process is well represented by an apparent kinetic of order 2.
Besides, Congo Red and Ethyl Violet are described by isotherms of type L and S respectively and that process is also well represented by the model of Langmuir for Ethyl Violet and Redlish-Peterson of Congo Red. On the other hand, the photocatalytic system led via TiO2/UV has been efficient toward both dyes and this process follows an apparent
rate constant of order 1. In another part, this process is well described by the kinetic model of Langmuir-Hinshelwood and that oxidation process occurs, mainly, in surface. The inhibition process has been demonstrated by alcohols proving thereby that radicals •OH are the main oxidation route. The photoproducts issued from the decolorization of the two dyes have been identified using masse spectroscopy technic. This has permitted to establish a mechanism of degradation for the two dyes. Same efficiency is obtained using CAZnO/UV process (CA: activated carbon issued from olive cakes). In another side and in the mixture, the treatment of the two dyes by both systems has, shown that the efficiency decreases as the concentration of the other added dye increases. Indeed, the addition of the second substrate slows down the disappearance speed of the other. The kinitics model
remained unchanged for the two processes (2nd order for adsorption and 1 st order for photocatalysis) The last part treats the degradation of the Monochloramine which occurs via direct UV photolysis in presence of two lamps:
BP (254 nm) and MP (200-600 nm).
The obtained results have been significant. Furthermore, these results have been greatly enhanced mainly by H2O2/UV. However, for NaOCl/UV system we could mention that the disappearance rate slows down because of the formation of photoproducts such as: Mono, Di and Trichloramines. Moreover, the process is well described by an apparent kinetic of order 1 and those photoproducts identified in H2O2/UV, NaOCl/UV and direct photolysis systems are nitrates and nitritesDiplôme : Doctorat en sciences En ligne : ../theses/chimie/ALA6959.pdf Format de la ressource électronique : Permalink : https://bu.umc.edu.dz/md/index.php?lvl=notice_display&id=10358 Elimination des polluants organiques par méthodes physicochimiques et photochimiques en milieux aqueux. : Cas de l’éthyle violet et du rouge congo (séparés et mélangés) et de la monochloramine [texte imprimé] / Abdessemed Ala, Auteur ; Kamel Djebbar, Auteur . - [S.l.] : جامعة الإخوة منتوري قسنطينة, 2016 . - 224 f. ; 30 cm.
2 copies imprimées disponibles
Langues : Français (fre)
Tags : Éthyle Violet Rouge Congo Mochloramine TiO2 Charbon actif ZnO Adsorption Rayonnement UV Photolyse H2O2 NaOCl •OH Ethyl violet Congo red Monochloramine Activated carbon UV radiation Photolysis Violet Ethyle) (Congo Rouge) ???????????? (NH2Cl) (PC500 TiO2) ????? ???? (ZnO) ?????? ???? ??? ??????? (H2O2) (NaOCl) (•OH ) (•Cl) Index. décimale : 540 Chimie et sciences connexes Résumé : The aim of this research is to study the decolorization of two dyes separated and in a mixture by physico-chemical processes (adsorption, TiO2 and CA-ZnO) and photocatalytic processes like: TiO2/UV and CA-ZnO/UV. Another study has been led on the degradation of Monocloramine in homogeneous phase via direct UV photolysis, H2O2/UV and
NaOCl/UV. Treated separately, both dyes have shown an appreciable adsorption on the two supports and that this process is well represented by an apparent kinetic of order 2.
Besides, Congo Red and Ethyl Violet are described by isotherms of type L and S respectively and that process is also well represented by the model of Langmuir for Ethyl Violet and Redlish-Peterson of Congo Red. On the other hand, the photocatalytic system led via TiO2/UV has been efficient toward both dyes and this process follows an apparent
rate constant of order 1. In another part, this process is well described by the kinetic model of Langmuir-Hinshelwood and that oxidation process occurs, mainly, in surface. The inhibition process has been demonstrated by alcohols proving thereby that radicals •OH are the main oxidation route. The photoproducts issued from the decolorization of the two dyes have been identified using masse spectroscopy technic. This has permitted to establish a mechanism of degradation for the two dyes. Same efficiency is obtained using CAZnO/UV process (CA: activated carbon issued from olive cakes). In another side and in the mixture, the treatment of the two dyes by both systems has, shown that the efficiency decreases as the concentration of the other added dye increases. Indeed, the addition of the second substrate slows down the disappearance speed of the other. The kinitics model
remained unchanged for the two processes (2nd order for adsorption and 1 st order for photocatalysis) The last part treats the degradation of the Monochloramine which occurs via direct UV photolysis in presence of two lamps:
BP (254 nm) and MP (200-600 nm).
The obtained results have been significant. Furthermore, these results have been greatly enhanced mainly by H2O2/UV. However, for NaOCl/UV system we could mention that the disappearance rate slows down because of the formation of photoproducts such as: Mono, Di and Trichloramines. Moreover, the process is well described by an apparent kinetic of order 1 and those photoproducts identified in H2O2/UV, NaOCl/UV and direct photolysis systems are nitrates and nitritesDiplôme : Doctorat en sciences En ligne : ../theses/chimie/ALA6959.pdf Format de la ressource électronique : Permalink : https://bu.umc.edu.dz/md/index.php?lvl=notice_display&id=10358 Exemplaires
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Titre : Etude de l’elimination des ions Cr(VI) par des procédés physico-chimiques application aux eaux de chromage Type de document : texte imprimé Auteurs : Imene Chaabna, Auteur ; Chahrazed Boukhalfa- Djebbar, Directeur de thèse Editeur : جامعة الإخوة منتوري قسنطينة Année de publication : 2017 Importance : 172 f. Format : 30 cm. Note générale : 2 copies imprimées disponibles
Langues : Français (fre) Tags : Cr(VI) traitement des eaux adsorption échange d’ions réduction charbon actif ferrihydrite composite (charbon actif/fer) Amberlite A21 Amberlite IRN78 eaux de chromage water treatment ion exchange reduction activated carbon composite (activated carbon/iron) chrome plating water "?????? ??????? ?????? ?????? ???????? ??????? ??????? ??????? ??? ???? ???? (???- ???? ) Index. décimale : 540 Chimie et sciences connexes Résumé : The present work focuses on the development of effective, practical and inexpensive physico-chemical processes for the decontamination of water containing Cr (VI) ions.
Adsorption removal was carried out using commercial activated charcoal, prepared ferrihydrite and composites (activated carbon/iron) prepared by precipitation of Fe (III) ions in the presence of coal at mass ratios (1/10) and 1/5). These adsorbents are characterized by DRX, ATR-FTIR, BET analysis, thermal analysis and by physicochemical analysis. The ion exchange removal is carried out using the Amberlite A21 resin (weak base type) and the Amberlite IRN78 resin (strong base type). The removal efficiency of Cr (VI) ions by precipitation after reduction is evaluated using ascorbic acid and sodium sulfite as reducing agents and soda and lime as precipitants.
In synthetic solutions, macroscopic experiments of Cr (VI) ions removal are carried out in the absence and in the presence of competitives ions in batch and in column (according the case). kinetics, equilibrium and thermodynamics studies are carried out.
The binding of Cr (VI) ions by adsorption is also studied through spectroscopic analysis. In chrome-plating waters, removal of Cr (VI) ions by these methods is evaluated as a function of pH The synthesized composites are characterized by the predominance of mesopores. Their specific surfaces are similar to that of ferrihydrite. Increasing the amount of iron involves increasing the content of basic functions and the formation of hematite.
The results of macroscopic experiments show that whatever the method used, the maximum elimination of Cr (VI) ions is recorded at acidic pH. The effectiveness of sodium sulfite in reducing Cr (VI) ions decreases rapidly with increasing pH. The increase in temperature implies an increase in the elimination in the case of the resins
and a decrease in the case of the adsorbents. The presence of competitive ions implies a decrease in the optimum pH range of the removal and a slowing down of adsorption and exchange processes. The removal efficiency of Cr (VI) ions by ferrihydrite, composites and resins is strongly influenced by the presence of sulfate ions.
The spectroscopic analysis (ATR-FTIR) suggest that the mechanism of Cr (VI) uptake by ferrihydrite and composites depends on pH and the presence of competitive ions. At pH <6, Cr (VI) ions form inner-sphere surface complexes. Whatever the pH, the interaction of the Cr (VI) ions is essentially electrostatic in the presence of the
competitive ions.
In chrome-plating waters, the efficiencies of Cr (VI) removal by the used solids at pH: 3 follow the order: IRN78> CAC> CACFe (1/5)> Ferrihydrite.
Diplôme : Doctorat En ligne : ../theses/chimie/CHA7019.pdf Format de la ressource électronique : Permalink : https://bu.umc.edu.dz/md/index.php?lvl=notice_display&id=10421 Etude de l’elimination des ions Cr(VI) par des procédés physico-chimiques application aux eaux de chromage [texte imprimé] / Imene Chaabna, Auteur ; Chahrazed Boukhalfa- Djebbar, Directeur de thèse . - [S.l.] : جامعة الإخوة منتوري قسنطينة, 2017 . - 172 f. ; 30 cm.
2 copies imprimées disponibles
Langues : Français (fre)
Tags : Cr(VI) traitement des eaux adsorption échange d’ions réduction charbon actif ferrihydrite composite (charbon actif/fer) Amberlite A21 Amberlite IRN78 eaux de chromage water treatment ion exchange reduction activated carbon composite (activated carbon/iron) chrome plating water "?????? ??????? ?????? ?????? ???????? ??????? ??????? ??????? ??? ???? ???? (???- ???? ) Index. décimale : 540 Chimie et sciences connexes Résumé : The present work focuses on the development of effective, practical and inexpensive physico-chemical processes for the decontamination of water containing Cr (VI) ions.
Adsorption removal was carried out using commercial activated charcoal, prepared ferrihydrite and composites (activated carbon/iron) prepared by precipitation of Fe (III) ions in the presence of coal at mass ratios (1/10) and 1/5). These adsorbents are characterized by DRX, ATR-FTIR, BET analysis, thermal analysis and by physicochemical analysis. The ion exchange removal is carried out using the Amberlite A21 resin (weak base type) and the Amberlite IRN78 resin (strong base type). The removal efficiency of Cr (VI) ions by precipitation after reduction is evaluated using ascorbic acid and sodium sulfite as reducing agents and soda and lime as precipitants.
In synthetic solutions, macroscopic experiments of Cr (VI) ions removal are carried out in the absence and in the presence of competitives ions in batch and in column (according the case). kinetics, equilibrium and thermodynamics studies are carried out.
The binding of Cr (VI) ions by adsorption is also studied through spectroscopic analysis. In chrome-plating waters, removal of Cr (VI) ions by these methods is evaluated as a function of pH The synthesized composites are characterized by the predominance of mesopores. Their specific surfaces are similar to that of ferrihydrite. Increasing the amount of iron involves increasing the content of basic functions and the formation of hematite.
The results of macroscopic experiments show that whatever the method used, the maximum elimination of Cr (VI) ions is recorded at acidic pH. The effectiveness of sodium sulfite in reducing Cr (VI) ions decreases rapidly with increasing pH. The increase in temperature implies an increase in the elimination in the case of the resins
and a decrease in the case of the adsorbents. The presence of competitive ions implies a decrease in the optimum pH range of the removal and a slowing down of adsorption and exchange processes. The removal efficiency of Cr (VI) ions by ferrihydrite, composites and resins is strongly influenced by the presence of sulfate ions.
The spectroscopic analysis (ATR-FTIR) suggest that the mechanism of Cr (VI) uptake by ferrihydrite and composites depends on pH and the presence of competitive ions. At pH <6, Cr (VI) ions form inner-sphere surface complexes. Whatever the pH, the interaction of the Cr (VI) ions is essentially electrostatic in the presence of the
competitive ions.
In chrome-plating waters, the efficiencies of Cr (VI) removal by the used solids at pH: 3 follow the order: IRN78> CAC> CACFe (1/5)> Ferrihydrite.
Diplôme : Doctorat En ligne : ../theses/chimie/CHA7019.pdf Format de la ressource électronique : Permalink : https://bu.umc.edu.dz/md/index.php?lvl=notice_display&id=10421 Exemplaires
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