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Titre : Cupric Oxide thin films deposition for gas sensor application Type de document : texte imprimé Auteurs : Meryem Lamri Zeggar, Auteur ; Mohamed Salah Aida, Directeur de thèse Editeur : جامعة الإخوة منتوري قسنطينة Année de publication : 2016 Importance : 225 f. Format : 30 cm. Note générale : 2 copies imprimées disponibles
Langues : Anglais (eng) Catégories : Français - Anglais
PhysiqueTags : couches minces CuO spray pyrolyse cellules solaire capteur à gaz thin films spray pyrolysis solar cells gas sensor شرائح رقيقة, CuOالرش الحرارى الخلايا الشمسية مجس الغازات Index. décimale : 530 Physique Résumé :
The present work deals with the deposition of CuO thin films by a simple and cheap
technique such as Spray ultrasonic pyrolysis (SP). In the first, a set of CuO thin film was prepared using various deposition conditions in order to optimize the technique and prepare suitable films devoted to the photovoltaic and sensing applications. The studied deposition parameters were the substrate temperature, flow rate, salt nature and concentration. The structural analysis shows that the obtained films are polycrystalline, they exhibit a monoclinic structure. The preferential orientation is strongly related to the experimental parameters studies. From the optical and electrical characterization results, we inferred that the deposited films have suitable optoelectronic properties for the photovoltaic applications since they present a good absorption in the visible range. The fabricated CuO based sensor show a very high sensitivity equivalent to 90% at lower operation temperature equal to 50°C towards 300 ppm of methanol vapor. The sensing layer exhibits response and recovery times of 2,45 min and 2,02 min respectively with limit detection equal to 20 ppm. For ethanol sensing, the CuO based gas sensor show a sensitivity equal to 45% towards 300 ppm concentration of ethanol at operation temperature equal to 150°C. Response and recovery times are 2,98 min and 2,11 min respectively with limit detection at 25 ppm. The fabricated CuO based gas sensor show also a relative gas response equal to 9% at lower operation temperature above 60°C for CO2 pressure at 5hPa. The response and recovery times are ranged from 29 to 41 s and 30 to 35 s respectively occurring increases in sensitivity from 4.67 to 13.46 % when varying the CO2 pressure from 2 to 20 hPa. The obtained solar cells devices for CuO/ZnO and CuO/ZnS have low efficiencies equal to 5.2 x 10-4 and 7 x 10-4 %, respectively.Diplôme : Doctorat En ligne : ../theses/physique/LAM6909.pdf Format de la ressource électronique : Permalink : index.php?lvl=notice_display&id=10244 Cupric Oxide thin films deposition for gas sensor application [texte imprimé] / Meryem Lamri Zeggar, Auteur ; Mohamed Salah Aida, Directeur de thèse . - جامعة الإخوة منتوري قسنطينة, 2016 . - 225 f. ; 30 cm.
2 copies imprimées disponibles
Langues : Anglais (eng)
Catégories : Français - Anglais
PhysiqueTags : couches minces CuO spray pyrolyse cellules solaire capteur à gaz thin films spray pyrolysis solar cells gas sensor شرائح رقيقة, CuOالرش الحرارى الخلايا الشمسية مجس الغازات Index. décimale : 530 Physique Résumé :
The present work deals with the deposition of CuO thin films by a simple and cheap
technique such as Spray ultrasonic pyrolysis (SP). In the first, a set of CuO thin film was prepared using various deposition conditions in order to optimize the technique and prepare suitable films devoted to the photovoltaic and sensing applications. The studied deposition parameters were the substrate temperature, flow rate, salt nature and concentration. The structural analysis shows that the obtained films are polycrystalline, they exhibit a monoclinic structure. The preferential orientation is strongly related to the experimental parameters studies. From the optical and electrical characterization results, we inferred that the deposited films have suitable optoelectronic properties for the photovoltaic applications since they present a good absorption in the visible range. The fabricated CuO based sensor show a very high sensitivity equivalent to 90% at lower operation temperature equal to 50°C towards 300 ppm of methanol vapor. The sensing layer exhibits response and recovery times of 2,45 min and 2,02 min respectively with limit detection equal to 20 ppm. For ethanol sensing, the CuO based gas sensor show a sensitivity equal to 45% towards 300 ppm concentration of ethanol at operation temperature equal to 150°C. Response and recovery times are 2,98 min and 2,11 min respectively with limit detection at 25 ppm. The fabricated CuO based gas sensor show also a relative gas response equal to 9% at lower operation temperature above 60°C for CO2 pressure at 5hPa. The response and recovery times are ranged from 29 to 41 s and 30 to 35 s respectively occurring increases in sensitivity from 4.67 to 13.46 % when varying the CO2 pressure from 2 to 20 hPa. The obtained solar cells devices for CuO/ZnO and CuO/ZnS have low efficiencies equal to 5.2 x 10-4 and 7 x 10-4 %, respectively.Diplôme : Doctorat En ligne : ../theses/physique/LAM6909.pdf Format de la ressource électronique : Permalink : index.php?lvl=notice_display&id=10244 Exemplaires (1)
Code-barres Cote Support Localisation Section Disponibilité LAM/6909 LAM/6909 Thèse Bibliothèque principale Thèses Disponible
Titre : Deposition of ZnO thin films for treatment of water. Type de document : texte imprimé Auteurs : Fouzia Bourfa, Auteur ; Nadhir Attaf, Directeur de thèse Mention d'édition : 27/12/2020 Editeur : جامعة الإخوة منتوري قسنطينة Année de publication : 2020 Importance : 199 f. Format : 30 cm. Note générale : 1 copies imprimées disponibles
Langues : Anglais (eng) Catégories : Français - Anglais
PhysiqueTags : physique:Sciences des matériaux Materials science: Semi-conductor Oxyde de Zinc Couches minces Nanostructuré Photocatalyse Activité antibactérienne Cellules solaires Zinc Oxide Thin films Nanostructured Photocatalysis Antibacterial activity Solar cells أكسيد الزنك الأغشية الرقيقة البنيةالنانوية التحفيز الضوئي النشاط المضاد للبكتيريا الخلايا الشمسية Index. décimale : 530 Physique Résumé :
The semiconductor heterogeneous photocatalytic technique is a kind of green technology that has been used to solve environmental pollution problems. The present study focuses on the screening of potentially photocatalytic ZnO thin films and nanostructures by using them to degrade organic dyes. Primarily Zinc chloride, nitrate and acetate salts were tested for their photocatalytic activity through the degradation of Red reactive and Methylene Blue (MB) in aqueous solution. The select compounds which are deposited by spray pyrolysis show considerable photodegradation efficiency. The studied different parameters such as concentration of dye, time deposition, salt source and seed layer position have a great effect on the photodegradation of this dye. Hydrothermal ZnO nanostructured were also tested for decolorization of MB and the results are very encourage especially for ZnO Nanorods (acetate salt) and ZnO nanoflowers for water treatment and gas sensing. Undoped and ZnO: Ag NPs films on glass and tissue, which prepared by sol-gel, show the capability of zinc oxide and silver nanoparticles to resist the growth of Gram – of K. pneumonia and E. coli by their inhibition zone which reaches 23 mm. Zinc nitrate as a precursor was used to prepare the Al/ ZnO/p-Si heterojunction by ultrasonic spray in order to investigate the photovoltaic parameters of the solar cell of this device. The I-V measurements indicate that the ideality factor n is 1.39 and the barrier height ϕb is 0.67 eV. The ϕb from I-V measurement and Norde’s function (0.69 eV) are in well agreement. While the series resistance Rs obtained from Norde’s function is found 1194 Ω. The diode has a good rectification property,photovoltaic behavior, photosensing and photoresponsivity properties. The electrical and photoelectric characterization confirms that this device is a very suitable candidate as a photodiode, photosensor applications and optoelectronic applications. The ISC and VOC were varied 11.12- 50.73 µA and 125.33- 185.22 mV for various illuminations. The C-V analysis shows that capacitance and conductance of the Al/ZnO/ p-Si diode depends on voltage and frequency. The Na, ϕb and Vbi of this structure are increased with the increasing frequencies.
Diplôme : Doctorat en sciences En ligne : ../theses/physique/BOU7776.pdf Format de la ressource électronique : Permalink : index.php?lvl=notice_display&id=11610 Deposition of ZnO thin films for treatment of water. [texte imprimé] / Fouzia Bourfa, Auteur ; Nadhir Attaf, Directeur de thèse . - 27/12/2020 . - جامعة الإخوة منتوري قسنطينة, 2020 . - 199 f. ; 30 cm.
1 copies imprimées disponibles
Langues : Anglais (eng)
Catégories : Français - Anglais
PhysiqueTags : physique:Sciences des matériaux Materials science: Semi-conductor Oxyde de Zinc Couches minces Nanostructuré Photocatalyse Activité antibactérienne Cellules solaires Zinc Oxide Thin films Nanostructured Photocatalysis Antibacterial activity Solar cells أكسيد الزنك الأغشية الرقيقة البنيةالنانوية التحفيز الضوئي النشاط المضاد للبكتيريا الخلايا الشمسية Index. décimale : 530 Physique Résumé :
The semiconductor heterogeneous photocatalytic technique is a kind of green technology that has been used to solve environmental pollution problems. The present study focuses on the screening of potentially photocatalytic ZnO thin films and nanostructures by using them to degrade organic dyes. Primarily Zinc chloride, nitrate and acetate salts were tested for their photocatalytic activity through the degradation of Red reactive and Methylene Blue (MB) in aqueous solution. The select compounds which are deposited by spray pyrolysis show considerable photodegradation efficiency. The studied different parameters such as concentration of dye, time deposition, salt source and seed layer position have a great effect on the photodegradation of this dye. Hydrothermal ZnO nanostructured were also tested for decolorization of MB and the results are very encourage especially for ZnO Nanorods (acetate salt) and ZnO nanoflowers for water treatment and gas sensing. Undoped and ZnO: Ag NPs films on glass and tissue, which prepared by sol-gel, show the capability of zinc oxide and silver nanoparticles to resist the growth of Gram – of K. pneumonia and E. coli by their inhibition zone which reaches 23 mm. Zinc nitrate as a precursor was used to prepare the Al/ ZnO/p-Si heterojunction by ultrasonic spray in order to investigate the photovoltaic parameters of the solar cell of this device. The I-V measurements indicate that the ideality factor n is 1.39 and the barrier height ϕb is 0.67 eV. The ϕb from I-V measurement and Norde’s function (0.69 eV) are in well agreement. While the series resistance Rs obtained from Norde’s function is found 1194 Ω. The diode has a good rectification property,photovoltaic behavior, photosensing and photoresponsivity properties. The electrical and photoelectric characterization confirms that this device is a very suitable candidate as a photodiode, photosensor applications and optoelectronic applications. The ISC and VOC were varied 11.12- 50.73 µA and 125.33- 185.22 mV for various illuminations. The C-V analysis shows that capacitance and conductance of the Al/ZnO/ p-Si diode depends on voltage and frequency. The Na, ϕb and Vbi of this structure are increased with the increasing frequencies.
Diplôme : Doctorat en sciences En ligne : ../theses/physique/BOU7776.pdf Format de la ressource électronique : Permalink : index.php?lvl=notice_display&id=11610 Exemplaires (1)
Code-barres Cote Support Localisation Section Disponibilité BOU/7776 BOU/7776 Thèse Bibliothèque principale Thèses Disponible
Titre : Élaboration et caracterisation des films ZnS par bain chimique Type de document : texte imprimé Auteurs : Hichem Lekiket, Auteur ; Mohamed Salah Aida, Directeur de thèse Editeur : جامعة الإخوة منتوري قسنطينة Année de publication : 2016 Importance : 116 f. Format : 30 cm. Note générale : 2 copies imprimes disponibles Langues : Français (fre) Catégories : Français - Anglais
PhysiqueTags : Science des matériaux semi-conducteurs Couches minces Sulfure de zinc Bain chimique Cellules solaires Thin films Zinc sulfide Chemical bath Solar cells الشرائح الرقيقة كبريتات الزنك بالحمام الكميائ الخلايا الشمسية Index. décimale : 530 Physique Résumé : The present work deals with the study of ZnS thin film synthesis by chemical bath deposition
technique (CBD). The latter is known to be cheap and simple which motivates our choice of
this method. We have used Zinc sulfate (ZnSO4), Thiourea (CS(NH2)2), ammonia (NH3) and
hydrazine (N2H4). thin films were prepared with two different parameters such as the pH
and the solution temperature. The structural, optical and electrical properties of the obtained
films were characterized by means of several techniques. From structural studies of ZnS films
we inferred that ZnS films have a cubic structure with a preferential orientation (111).
The optical studies reveal that ZnS films have a large transparency in the visible range. This
comforts their using as buffer layer in thin films solar cells.Diplôme : Doctorat en sciences En ligne : ../theses/physique/LEK6849.pdf Format de la ressource électronique : Permalink : index.php?lvl=notice_display&id=10146 Élaboration et caracterisation des films ZnS par bain chimique [texte imprimé] / Hichem Lekiket, Auteur ; Mohamed Salah Aida, Directeur de thèse . - جامعة الإخوة منتوري قسنطينة, 2016 . - 116 f. ; 30 cm.
2 copies imprimes disponibles
Langues : Français (fre)
Catégories : Français - Anglais
PhysiqueTags : Science des matériaux semi-conducteurs Couches minces Sulfure de zinc Bain chimique Cellules solaires Thin films Zinc sulfide Chemical bath Solar cells الشرائح الرقيقة كبريتات الزنك بالحمام الكميائ الخلايا الشمسية Index. décimale : 530 Physique Résumé : The present work deals with the study of ZnS thin film synthesis by chemical bath deposition
technique (CBD). The latter is known to be cheap and simple which motivates our choice of
this method. We have used Zinc sulfate (ZnSO4), Thiourea (CS(NH2)2), ammonia (NH3) and
hydrazine (N2H4). thin films were prepared with two different parameters such as the pH
and the solution temperature. The structural, optical and electrical properties of the obtained
films were characterized by means of several techniques. From structural studies of ZnS films
we inferred that ZnS films have a cubic structure with a preferential orientation (111).
The optical studies reveal that ZnS films have a large transparency in the visible range. This
comforts their using as buffer layer in thin films solar cells.Diplôme : Doctorat en sciences En ligne : ../theses/physique/LEK6849.pdf Format de la ressource électronique : Permalink : index.php?lvl=notice_display&id=10146 Exemplaires (1)
Code-barres Cote Support Localisation Section Disponibilité LEK/6849 LEK/6849 Thèse Bibliothèque principale Thèses Disponible Etude structurale et optique de films minces ZnO élaborés par voie physique et/ou chimique / Adel Taabouche
Titre : Etude structurale et optique de films minces ZnO élaborés par voie physique et/ou chimique Type de document : texte imprimé Auteurs : Adel Taabouche, Auteur ; A. Bouabellou, Directeur de thèse Editeur : Constantine : Université Mentouri Constantine Année de publication : 2015 Importance : 107 f. Format : 30 cm. Note générale : 2 copies imprimées disponibles
Langues : Français (fre) Catégories : Français - Anglais
PhysiqueTags : Sciences des matériaux Couche mince ZnO PLD Spray DRX AFM RBS M-lines UV-visible Effet Hall Thin films XRD Hall Effect شرائح رقیقة أكسید الزنك الإستئصال اللیزري الرش فوق الصوتي انحراف الأشعة
السینسة مطیافیة رذرفورد مطیافیة الخطوط السوداء أثر ھولIndex. décimale : 530 Physique Résumé : In the present work, we have studied essentially the structural and optical properties of ZnO thin films elaborated using the physical technique s of the pulsed laser ablation (PLD) and the chemical method of the ultrasonic spray pyrolysis.
We have prepared undoped (ZnO) and cobalt-doped zinc oxide (CZO) thin films (Co: 3,5 at.%) by means of the PLD method. Synthesized films have been deposited on glass and silicon substrates heated at 450°C. The used source was a KrF eximer laser (248 nm, 25 ns, 2 J ⁄cm2). Different experimental techniques have been carried out to analyze the fabricated films: the X-ray diffraction (XRD), atomic force microscopy (AFM), Rutherford Backscattering spectrometry (RBS), UV-visible spectrophotometry, M-lines
spectroscopy and Hall effect.
While the ZnO films obtained by the ultrasonic spray technique have been deposited with different deposition times (10, 20, 30 min) on a glass substrate heated at 410 °C, and then they have characterized by XRD, AFM, UV-visible, M-lines and hall effect techniques.
The carried out study shows that all the prepared zinc oxide films have a hexagonal wurtzite-type structure and a preferentially oriented along the direction (002) confused with the c-axis perpendicular to the surface of the substrates. The grain sizes deducted from the XRD measurements vary between 24 and 40 nm. The optical coupling analysis realized by M-lines show that the ZnO films are monomode (for both TE and TM polarizations). However, the undoped ZnO film obtained by PLD is found to be two
guiding modes for TM. The films obtained have an optical transmission of 70 to 90% in the visible region of the spectrum and an optical band gap varying from 3.18 to 3.37 eV.
The electrical conductivity and the concentration of carriers, deduced from Hall effect measurements, are relatively low namely for the films prepared by spray pyrolysis technique.
Diplôme : Doctorat en sciences En ligne : ../theses/physique/TAA6719.pdf Format de la ressource électronique : Permalink : index.php?lvl=notice_display&id=9904 Etude structurale et optique de films minces ZnO élaborés par voie physique et/ou chimique [texte imprimé] / Adel Taabouche, Auteur ; A. Bouabellou, Directeur de thèse . - Constantine : Université Mentouri Constantine, 2015 . - 107 f. ; 30 cm.
2 copies imprimées disponibles
Langues : Français (fre)
Catégories : Français - Anglais
PhysiqueTags : Sciences des matériaux Couche mince ZnO PLD Spray DRX AFM RBS M-lines UV-visible Effet Hall Thin films XRD Hall Effect شرائح رقیقة أكسید الزنك الإستئصال اللیزري الرش فوق الصوتي انحراف الأشعة
السینسة مطیافیة رذرفورد مطیافیة الخطوط السوداء أثر ھولIndex. décimale : 530 Physique Résumé : In the present work, we have studied essentially the structural and optical properties of ZnO thin films elaborated using the physical technique s of the pulsed laser ablation (PLD) and the chemical method of the ultrasonic spray pyrolysis.
We have prepared undoped (ZnO) and cobalt-doped zinc oxide (CZO) thin films (Co: 3,5 at.%) by means of the PLD method. Synthesized films have been deposited on glass and silicon substrates heated at 450°C. The used source was a KrF eximer laser (248 nm, 25 ns, 2 J ⁄cm2). Different experimental techniques have been carried out to analyze the fabricated films: the X-ray diffraction (XRD), atomic force microscopy (AFM), Rutherford Backscattering spectrometry (RBS), UV-visible spectrophotometry, M-lines
spectroscopy and Hall effect.
While the ZnO films obtained by the ultrasonic spray technique have been deposited with different deposition times (10, 20, 30 min) on a glass substrate heated at 410 °C, and then they have characterized by XRD, AFM, UV-visible, M-lines and hall effect techniques.
The carried out study shows that all the prepared zinc oxide films have a hexagonal wurtzite-type structure and a preferentially oriented along the direction (002) confused with the c-axis perpendicular to the surface of the substrates. The grain sizes deducted from the XRD measurements vary between 24 and 40 nm. The optical coupling analysis realized by M-lines show that the ZnO films are monomode (for both TE and TM polarizations). However, the undoped ZnO film obtained by PLD is found to be two
guiding modes for TM. The films obtained have an optical transmission of 70 to 90% in the visible region of the spectrum and an optical band gap varying from 3.18 to 3.37 eV.
The electrical conductivity and the concentration of carriers, deduced from Hall effect measurements, are relatively low namely for the films prepared by spray pyrolysis technique.
Diplôme : Doctorat en sciences En ligne : ../theses/physique/TAA6719.pdf Format de la ressource électronique : Permalink : index.php?lvl=notice_display&id=9904 Exemplaires (1)
Code-barres Cote Support Localisation Section Disponibilité TAA/6719 TAA/6719 Thèse Bibliothèque principale Thèses Disponible
Titre : Realization and electrical characterization of thin film heterojunction for photovoltaic application. Type de document : texte imprimé Auteurs : Fatima Zohra Boutebakh, Auteur ; Nadhir Attaf, Directeur de thèse Editeur : جامعة الإخوة منتوري قسنطينة Année de publication : 2018 Importance : 173 f. Format : 30 cm. Note générale : 2 copies imprimées disponibles
Langues : Anglais (eng) Catégories : Français - Anglais
PhysiqueTags : couches minces CZTS spray pyrolyse hétérojonction cellules solaire thin films spray pyrolysis hetero-junction solar cells شرائح رقيقة CZTSالرش الحرارى وصلة غير متجانسة الخلايا الشمسية Index. décimale : 530 Physique Résumé : The present work deals with the deposition of CZTS thin films and related devices by a simple and cheap technique such as Spray Pyrolysis (SP). For this purpose, a set of CZTS thin film was prepared using various deposition conditions in order to optimize the deposition conditions allow us to prepare suitable films devoted to the photovoltaic applications. The studied deposition parameters were the substrate temperature, deposition time, and copper and zinc salt concentrations. The structural analysis shows that the obtained films are polycrystalline; they exhibit a tetragonal structure with a preferential orientation along (112). However, the structural properties and secondary phases were affected by the deposition conditions. From the optical and electrical characterization results, we inferred that the deposited films have suitable optoelectronic properties for the photovoltaic applications, since they present a good absorption in the visible range coupled with a higher conductivity. Finally; the fabricated CZTS heterojunction with various back contacts show a rectification behavior, the G-f characterization reveals the presence of interface state at CZTS/ZnS interface with a state density in the order of 1010 eV-1cm-2. The addition of ZnO intrinsic layer enhances the heterojunction device properties. Whereas, the solar cells based CZTS/CdS annealed at 450 °C under H2S gas show the best solar cell efficiency about 0.43 % and a current density equal 9.8 mA/cm2.
Diplôme : Doctorat En ligne : ../theses/physique/BOU7355.pdf Format de la ressource électronique : Permalink : index.php?lvl=notice_display&id=11004 Realization and electrical characterization of thin film heterojunction for photovoltaic application. [texte imprimé] / Fatima Zohra Boutebakh, Auteur ; Nadhir Attaf, Directeur de thèse . - جامعة الإخوة منتوري قسنطينة, 2018 . - 173 f. ; 30 cm.
2 copies imprimées disponibles
Langues : Anglais (eng)
Catégories : Français - Anglais
PhysiqueTags : couches minces CZTS spray pyrolyse hétérojonction cellules solaire thin films spray pyrolysis hetero-junction solar cells شرائح رقيقة CZTSالرش الحرارى وصلة غير متجانسة الخلايا الشمسية Index. décimale : 530 Physique Résumé : The present work deals with the deposition of CZTS thin films and related devices by a simple and cheap technique such as Spray Pyrolysis (SP). For this purpose, a set of CZTS thin film was prepared using various deposition conditions in order to optimize the deposition conditions allow us to prepare suitable films devoted to the photovoltaic applications. The studied deposition parameters were the substrate temperature, deposition time, and copper and zinc salt concentrations. The structural analysis shows that the obtained films are polycrystalline; they exhibit a tetragonal structure with a preferential orientation along (112). However, the structural properties and secondary phases were affected by the deposition conditions. From the optical and electrical characterization results, we inferred that the deposited films have suitable optoelectronic properties for the photovoltaic applications, since they present a good absorption in the visible range coupled with a higher conductivity. Finally; the fabricated CZTS heterojunction with various back contacts show a rectification behavior, the G-f characterization reveals the presence of interface state at CZTS/ZnS interface with a state density in the order of 1010 eV-1cm-2. The addition of ZnO intrinsic layer enhances the heterojunction device properties. Whereas, the solar cells based CZTS/CdS annealed at 450 °C under H2S gas show the best solar cell efficiency about 0.43 % and a current density equal 9.8 mA/cm2.
Diplôme : Doctorat En ligne : ../theses/physique/BOU7355.pdf Format de la ressource électronique : Permalink : index.php?lvl=notice_display&id=11004 Exemplaires (1)
Code-barres Cote Support Localisation Section Disponibilité BOU/7355 BOU/7355 Thèse Bibliothèque principale Thèses Disponible Permalink
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